Piquionne will not be eligible to play for Doncaster when they visit the Boleyn Ground on Sunday.
The 33-year-old Frenchmen has made 21 appearances for Sam Allardyce’s team this season but has only found the net on two occasions.
The arrival of Ricardo Vaz Te and Nicky Maynard in the January transfer window has made the likelihood of a return to the first-team very slim for Piquionne.